Another very interesting pic Brian. I have this volume with it's reproduction of an attractive painting on the cover,
As well as Maldon it also covers some of the workings on the Braintree branch, originally the same railway. There is not one picture of an F6 on a train, they were barred from the Witham to Maldon direct route but were permitted via Woodham Ferrers and also to Braintree. The locomotive notes in the book suggest that in late LNER and early BR days the F6s were used when a shortage of F5s occurred, the Colchester shed foreman turning a Nelsonian eye to the route restrictions. This suggests two things , Tim's picture is of a relatively rare occasion and that it is a Colchester engine. In 1956 there were only three F6 engines allocated to Colchester, 67225, 67227 until 3/6/56, and 67228 from 4/3/56, therefore I would concur that it is most likely 67227, 67223 was a Lowestoft engine so could as an outsider be considered.
Re fitting of vacuum equipment to air braked engines, it seems the LNER policy was that vacuum equipment for locos in air braked areas, principally the GE , NE, and NB, was superimposed on top of whatever other equipment was fitted with minimum alteration to existing bits, presumably on a cost consideration, although for example the early Shires allocated to Scotland when vacuum fitted had the air pumps removed and the air assisted reversers converted (poorly I may say) to screw operation and the loco braking changed to steam operation, so it's not a hard and fast rule. Neither they nor BR managed to rid the GE section of the air brake, advanced Stratford thinking.
As far as I am aware, purely from anecdotal evidence, the Southern whilst retaining air braking tended to make this straight air rather than Westinghouse and removed train braking capability altogether, I might be on dodgy ground here so don't quote me.
Best wishes
Martin